Carbocyclic ring closure of unsaturated S-, Se-, and C-aryl glycosides

DOI: 10.1002/(SICI)1521-3773(20000117)39:2<362::AID-ANIE362>3.0.CO;2-1

Source and publish data:

Angewandte Chemie - International Edition p. 362 - 364 (2000)

Update date:2022-09-26

Topics:

Authors:

Sollogoub, Matthieu

Mallet, Jean-Maurice

Sinay, Pierre

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Article abstract of DOI:10.1002/(SICI)1521-3773(20000117)39:2<362::AID-ANIE362>3.0.CO;2-1

Triisobutylaluminum-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons - such as C-aryl glycoside 1, or O-, S- , and Seglycosides - provides direct access to highly functionalized cyclohexane derivatives such as 2.

Full text of DOI:10.1002/(SICI)1521-3773(20000117)39:2<362::AID-ANIE362>3.0.CO;2-1

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