89656-98-4

Basic information

• Product Name: Cyclohexane, (2-methyl-1-propenyl)-
• Synonyms: 3-cyclohexyl-2-methyl-2-propene;3-cyclohexyl-2-methylprop-2-ene
• CAS NO: 89656-98-4
• Molecular Formula: C10H18
• Molecular Weight: 138.253
• Mol File: 89656-98-4.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Cyclohexane, (2-methyl-1-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, (2-methyl-1-propenyl)-(89656-98-4)
• EPA Substance Registry System: Cyclohexane, (2-methyl-1-propenyl)-(89656-98-4)

Safety Data

• Hazardous Substances Data: 89656-98-4(Hazardous Substances Data)

Upstream product

• 24470-78-8 isopropyltriphenylphosphonium iodide 
• 2043-61-0 cyclohexanecarbaldehyde 
• 626-62-0 Cyclohexyl iodide 
• 38614-36-7 2-methylpropen-1-ylmagnesium bromide 
• 542-18-7 cyclohexyl chloride 
• 24371-94-6 cyclohexylmercury chloride 
• 23010-28-8 2,2-dimethylethenylmercury bromide 
• 108-85-0 1-bromocyclohexane 
• 3017-69-4 2-methyl-1-propenylbromide 
• 20687-01-8 1-iodo-2-methylpropene 
• 931-51-1 cyclohexylmagnesiumchloride 
• 90047-75-9 1-Iodo-8-methyl-6,7-nonadiene 

Downstream Products

• 91975-66-5 2,2-Dimethyl-3-trans-cyclohexyl-cyclopropan-carbonsaeure-⁽¹⁾-methylester 

Relevant articles and documents

Direct Cross-Coupling of Allylic C(sp3)?H Bonds with Aryl- and Vinylbromides by Combined Nickel and Visible-Light Catalysis

An efficient protocol for the direct allylic C(sp3)?H bond activation of unactivated tri- and tetrasubstituted alkenes and their functionalization with aryl- and vinylbromides by nickel and visible-light photocatalysis has been developed. The method allows C(sp2)?C(sp3) formation under mild reaction conditions with good functional-group tolerance and excellent regioselectivity.

Iron-catalyzed negishi coupling toward an effective olefin synthesis

A selective Iron-catalyzed cross-coupling of alkyl halldes with alkenylzinc reagents Is described. Primary and secondary alkyl chlorides, bromides, and iodides take part In the reaction to give the corresponding olefins In good to excellent yields In a stereospecific manner. High functional group compatibility Is also demonstrated by using combinations of substrates possessing rather reactive substituents.

Iron-catalyzed cross-coupling of alkyl halides with alkenyl Grignard reagents

(Chemical Equation Presented) Cheap and safe: An iron-catalyzed cross-coupling reaction between alkyl halides and alkenyl Grignard reagents is described. This C-C bond coupling reaction is promoted by the cheap and nontoxic FeCl3 and displays good tolerance against various functional groups.