89668-85-9Relevant academic research and scientific papers
CLEAVAGE OF THE CARBON-SILICON BONDS IN TRIMETHYLSILYLACETYLENES BY trans-PF6 CATIONS AND FORMATION OF CATIONIC ALKOXYCARBENE COMPLEXES OF PLATINUM (II)
Clark, H.C.,Jain, V.K.,Rao, G.S.
, p. 275 - 282 (1983)
Cationic alkoxycarbene complexes of platinum(II) have been isolated in the reactions of trans-PF6 (X=H or Me; R'=Me or Et) with Me3SiCCR'' (R''=H, Me or SiMe3).In these reactions cleavage of the carbon-silicon bond by the nuclophilic a
