89703-82-2Relevant academic research and scientific papers
SILYLATED THIIRAN-1-OXIDES: STRUCTURE, RING OPENING AND CONVERSION TO A BENZOTHIOPHENE.
Bonini, Bianca F.,Foresti, Elisabetta,Leardini, Rino,Maccagnani, Gaetano,Mazzanti, Germana
, p. 445 - 448 (1984)
Silylated thiirans upon oxidation with peroxyacids do not give exclusively the corresponding S-oxides but, in addition, some products derived from ring opening.The stereochemistry of the oxidation to thiiran-1-oxides is anti to the silyl group as demonstr
