SILYLATED THIIRAN-1-OXIDES: STRUCTURE, RING OPENING AND CONVERSION TO A BENZOTHIOPHENE.

DOI: 10.1016/S0040-4039(00)99907-6

Source and publish data:

Tetrahedron Letters p. 445 - 448 (1984)

Update date:2022-08-04

Topics:

Authors:

Bonini, Bianca F.

Foresti, Elisabetta

Leardini, Rino

Maccagnani, Gaetano

Mazzanti, Germana

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Article abstract of DOI:10.1016/S0040-4039(00)99907-6

Silylated thiirans upon oxidation with peroxyacids do not give exclusively the corresponding S-oxides but, in addition, some products derived from ring opening.The stereochemistry of the oxidation to thiiran-1-oxides is anti to the silyl group as demonstr

Full text of DOI:10.1016/S0040-4039(00)99907-6

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