89720-98-9Relevant academic research and scientific papers
Regioselective reactions of o-aminothiophenol with unsymmetrical maleic anhydrides
Balasubramaniyan, V.,Balasubramaniyan, P.,Shaikh, A. S.,Argade, N. P.
, p. 123 - 125 (2007/10/02)
Maleic anhydride (MA; Ia) and its methyl (MMA; Ib), dimethyl (DMMa; Ic), phenyl (PMA; Id) and phenylmethyl (PMMA; Ie) derivatives react with o-aminothiophenol (o-ATP) to yield benzothiazines (IIIa-e) via Michael-type addition.In contrast, its oxygenated derivatives react with o-ATP to furnish benzothiazoles (IVf-h) apparently by a different pathway.
Reactions of Cyclic Anhydrides: Part VIII - Formation of 2-Oxobenzothazines from o-Aminothiophenol and Maleic Anhydride Derivatives
Wagh, S. B.,Shaikh, A. S.,Balasubramaniyan, V.
, p. 868 - 871 (2007/10/02)
Reaction of o-aminothiophenol (o-ATP) with maleic anhydride, maleic acid or fumaric acid furnishes 2-(oxobenzothiazinyl)acetic acid (Ia); with methyl hydrogenmaleate or methyl hydrogenfumarate, a mixture of Ia and its methyl ester Ib (80 : 20 and 65 : 35
