89729-99-7Relevant academic research and scientific papers
New Synthetic Methods, 10. - β-Ketosulfones, Useful Ethylenediide Equivalents: The Synthesis of Unsaturated Carboxylic Acids
Scholz, Dieter
, p. 264 - 272 (2007/10/02)
α-Alkyl-thiolated cycloalkanones are, after oxidation to sulfones, ring-opened by halogenation to yield α-halosulfones.Ramberg-Baecklund rearrangement forms unsaturated carboxylic acids.The position of the newly formed double bond is fixed by the ring siz
