89730-33-6Relevant academic research and scientific papers
Aryne triggered [2,3]-sigmatropic rearrangement of allyl and propargyl thioethers
Tan, Jiajing,Zheng, Tianyu,Xu, Kun,Liu, Changyao
supporting information, p. 4946 - 4950 (2017/07/10)
An efficient protocol for [2,3]-sigmatropic rearrangement of allyl and propargyl thioethers is reported. The key sulfonium ylide intermediate is in situ formed via S-arylation of arynes. This transition metal-free method allows for ready access to a wide
Synthesis of Functionalized β-Keto Arylthioethers by the Aryne Induced [2,3] Stevens Rearrangement of Allylthioethers
Thangaraj, Manikandan,Gaykar, Rahul N.,Roy, Tony,Biju, Akkattu T.
, p. 4470 - 4476 (2017/04/28)
A mild and transition-metal-free synthesis of β-keto arylthioethers has been developed by the aryne triggered [2,3] Stevens rearrangement of allylthioethers. The key sulfur ylide intermediate for the rearrangement was formed by the S-arylation of allylthi
New Synthetic Methods, 9. - S-Alkyl 4-Methylbenzenethiosulfonates, Excellent Reagents for α-Thiolation of Cyclic Ketones
Scholz, Dieter
, p. 259 - 263 (2007/10/02)
S-Alkyl 4-methylbenzenethiosulfonates, easily prepared by alkylation of commercially available potassium 4-methylbenzenethiosulfonate in dry dimethylformamide, thiolate enolates of cyclic ketones in α position in high yield.
