89738-83-0Relevant articles and documents
Synthesis, Structure, and Some Reactions of (2,4,6-Tri-t-butyl)thiobenzaldehyde, the First Stable Aromatic Thioaldehyde
Ishii, Akihiko,Ishida, Takashi,Kumon, Naoko,Fukuda, Nobuo,Oyama, Hiroyuki,Inamoto, Naoki,Iwasaki, Fujiko,Okazaki, Renji
, p. 709 - 717 (2007/10/03)
The title compound 1 was synthesized by the reaction of 2,4,6-tri-t-butylphenyllithium with O-ethyl thioformate or that of 2,4,6-tri-t-butylbenzaldehyde hydrazone with disulfur dichloride in the presence of triethylamine. The thioaldehyde 1 is a purple cr
NEW ASPECTS OF ORGANOSELENIUM COMPOUNDS CONTAINING GROUP 14 ELEMENTS
Okazaki, Renji,Tokitoh, Norihiro,Ishii, Akihiko,Ishii, Naoko,Matsuhashi, Yasusuke,et al.
, p. 49 - 66 (2007/10/02)
The synthesis and reactivities of double bond compounds between Group 14 and Group 16 elements have been reported.Specifically the chemistry of M=X type compounds (C=Se, Ge=S, Sn=S, Sn=Se) are described.
REACTIONS OF A STABLE THIOBENZALDEHYDE WITH ORGANOMETALLICS
Okazaki, Renji,Fukuda, Nobuo,Oyama, Hiroyuki,Inamoto, Naoki
, p. 101 - 104 (2007/10/02)
Rections of 2,4,6-tri-t-butylthiobenzaldehyde with Grignard and organolithium reagents gave products via the anion radical of the thioaldehyde.The first example of dimerization of thioketyl radicals was also presented.