897400-50-9

Basic information

• Product Name: Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2
• CAS NO: 897400-50-9
• Molecular Weight: 503.611
• Mol File: 897400-50-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2(CAS DataBase Reference)
• NIST Chemistry Reference: Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2(897400-50-9)
• EPA Substance Registry System: Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2(897400-50-9)

Safety Data

• Hazardous Substances Data: 897400-50-9(Hazardous Substances Data)

Upstream product

• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 6323-18-8 2-chloropropiophenone 
• 672-66-2 Dimethyl(phenyl)phosphine 

Relevant articles and documents

Self-addition of metallacydic nickel enolate complexes stabilized by monodentate phosphine ligands

In contrast with their stable counterparts bearing the chelating diphosphines, the nickelacyclic O-enolate complexes stabilized by monodentate ligands Ni(OC(CHR)-o-C6H4)L2 (R = H, Me, L = PMe3; R = H, L = PMe2Ph) undergo an unusual self-addition process leading to dinuclear alkoxo-hydroxo derivatives. The α-substituted enolate complexes (R = Me) are less prone to undergo this transformation, and the corresponding nickelacycles with L = PMe3 or PMe2Ph can be isolated in pure form.