89795-55-1

Basic information

• Product Name: Benzamide, 2-nitroso- (9CI)
• Synonyms: Benzamide, 2-nitroso- (9CI)
• CAS NO: 89795-55-1
• Molecular Formula: C₇H₆N₂O₂
• Molecular Weight: 150.13474
• Product Categories: AMIDE
• Mol File: 89795-55-1.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzamide, 2-nitroso- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 2-nitroso- (9CI)(89795-55-1)
• EPA Substance Registry System: Benzamide, 2-nitroso- (9CI)(89795-55-1)

Safety Data

• Hazardous Substances Data: 89795-55-1(Hazardous Substances Data)

Upstream product

• 610-15-1 2-nitrobenzamide 

Downstream Products

• 123534-30-5 1-(4'-methylphenylsulfonyl)-2,1-benzisoxazol-3(1H)-one 
• 1159-86-0 o-dibenzoylbenzene 

Relevant articles and documents

Electrosynthesis and in situ chemical rearrangement of o-nitrosobenzamides

Primary and secondary o-nitrosobenzamides can be prepared in a "redox" cell but are unstable in the solvent used for electrolysis (acetate buffer-alcohol).At room temperature N-aryl-2-nitrosobenzamides give 2-carboxyazobenzenes.N-alkyl-2-nitrosobenzamides decompose thermally into 2-methoxy or 2-ethoxycarbonylphenylhydrazones according to the alcohol used.Similarly, methyl benzoate (or ethyl benzoate) is obtained from 2-nitrosobenzamide.A possible mechanism involves an unstable heterocycle formed by the coupling of the two nitrogen atoms (nitroso and amide) followed by cleavage of the carbonyl-nitrogen bond resulting from nucleophilic attack of the solvent (water or alcohol). Key Words: flow cell electrosynthesis / 2-nitrosobenzamides / 2-carboxyazobenzenes / 2-alkoxycarbonylphenylhydrazones / indazol-3-one