89809-41-6Relevant academic research and scientific papers
FUNCTIONAL ALLYLSILANES: REACTIVITY OF PYRROLIDINOALLYLSILANES TOWARDS ELECTROPHILES
Corriu, R.J.P.,Huynh, V.,Moreau, J.J.E.
, p. 283 - 294 (1983)
(3-Pyrrolidinoallyl)trimethylsilane (1) and (1-pyrrolidinoallyl)trimethylsilane (2) have been prepared from allylpyrrolidine.Compound 1 is both an allylsilane and an enamine.It exhibits enamine-type reactions with electrophiles leading to substituted β-tr
Synthesis of 3-silyl-2(5H)-furanone by rhodium-catalyzed cyclocarbonylation
Fukuta, Yukimasa,Matsuda, Isamu,Itoh, Kenji
, p. 1301 - 1304 (2001)
3-Silyl-2(5H)-furanones are readily formed by the rhodium-catalyzed cyclocarbonylation of propargyl alcohol derivatives bearing a trialkylsilyl group on the terminal sp-carbon under hydroformylation conditions. The following two requirements must be satisfied for the success of this protocol; (i) the presence of a silyl group on the sp-carbon, and (ii) the presence of a catalytic amount of Rh4(CO)12.
