89844-08-6

Basic information

• Product Name: Benzoic acid, 2-(2-propenyloxy)-, 2-propenyl ester
• CAS NO: 89844-08-6
• Molecular Formula: C13H14O3
• Molecular Weight: 218.252
• Mol File: 89844-08-6.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-(2-propenyloxy)-, 2-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-(2-propenyloxy)-, 2-propenyl ester(89844-08-6)
• EPA Substance Registry System: Benzoic acid, 2-(2-propenyloxy)-, 2-propenyl ester(89844-08-6)

Safety Data

• Hazardous Substances Data: 89844-08-6(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 107-18-6 allyl alcohol 
• 151414-76-5 o-(prop-2-enyloxy)phenylboronic acid 
• 106-95-6 allyl bromide 
• 69-72-7 salicylic acid 

Downstream Products

• 16982-86-8 3-methyl-chroman-4-one 
• 1454663-48-9 diethyl (2-(allyloxy)benzoyl)phosphonate 
• 1613331-67-1 2-oxopropyl 2-(2-oxopropoxy)benzoate 
• 167864-75-7 methyl 2-diazo-3-(2-allyloxyphenyl)-3-oxopropionate 
• 167864-65-5 2-(2-Allyloxy-benzoyl)-acrylic acid methyl ester 
• 52542-42-4 2-allyloxybenzoyl chloride 
• 69-72-7 salicylic acid 
• 10484-09-0 allyl salicylate 
• 59086-52-1 2-allyloxybenzoic acid 

Relevant articles and documents

Cobalt-catalyzed cyclization with the introduction of cyano, acyl and aminoalkyl groups

An efficient synthesis of carbo-and heterocycles using CC, CO and CN bonds under cobalt catalysis is described. The substituents on olefins are key for controlling the regio-and chemoselectivity in the initial hydrogen atom transfer step and quaternary carbons are efficiently constructed under mild conditions. Cyclopropane cleavage and tandem cyclization give highly functionalized bicyclic skeletons in a single operation.

Observations concerning the synthesis of heteroatom-containing 9-membered benzo-fused rings by ring-closing metathesis

A set of benzo-fused dienes with a 1,9-relationship and containing a variety of nitrogen and oxygen heteroatoms was readily synthesized. These dienes were then treated with the Grubbs second generation catalyst with the aim of synthesizing the 9-membered benzannelated heterocycles containing two heteroatoms (either O,O, NR,NR or O,NR where R = Ts or Boc). As previously observed in the literature, many of the dienes did not give the expected ring-closed product. However, a number of the desired products did form, namely with the 1,2-dihydrobenzo[c][1,5]oxazonin-7(5H)-one, 5,7-dihydrobenzo[b][1,5]oxazonine-6(2H)-carboxylate and 2,5,6,7-tetrahydrobenzo[b][1,5]oxazonine cores, albeit in poor yields. Rather surprisingly, the N-allyl-N-(2-(N-allyl-4-methylphenylsulfonamido)benzyl)-4-methylbenzenesulfonamide scaffold gave the desired ring-closed 1,6-ditosyl-2,5,6,7-tetrahydro-1H-benzo[b][1,5]diazonine in a high yield. Furthermore, when treated with the catalyst [RuClH(CO)(PPh3)3] the alkene isomerized into conjugation only with the benzylic NTs group and not with the phenyl NTs group to afford the 1,6-ditosyl-2,3,6,7-tetrahydro-1H-benzo[b][1,5]diazonine structure.

Synthesis and Physical Properties of Thiol-Ene Networks Utilizing Plant-Derived Phenolic Acids

Elastomeric polymer films synthesized through thiol-ene chemistry, suitable in applications as coatings and adhesives due to their ease of preparation and superior physical properties, are traditionally derived from petroleum sources. Of recent interest i