89861-16-5Relevant academic research and scientific papers
Rapid construction of the aza-propellane core of acutumine via a photochemical [2 + 2] cycloaddition reaction
Navarro, Raul,Reisman, Sarah E.
supporting information, p. 4354 - 4357 (2012/11/07)
Synthetic efforts toward the chlorinated aza-propellane alkaloid acutumine (1) are described. The key vicinal quaternary centers were constructed by a photochemical [2 + 2] cycloaddition reaction of a furanyl-tetrahydroindolone. Dihydroxylation of the [2
3-ALKYLFURANS AS USEFUL SYNTHETIC EQUIVALENTS FOR SUBSTITUTED Δ2-BUTENOLIDES
Goldsmith, David,Liotta, Dennis,Saindane, Manohar,Waykole, Liladhar,Bowen, Phillip
, p. 5835 - 5838 (2007/10/02)
Substituted Δ2-butenolides may be prepared from furan equivalents by regiospecific metallation, sulfenylation and/or silylation, removal of the sulfur group and peracid oxidation.
