89863-03-6Relevant academic research and scientific papers
Modified boehmite: A choice of catalyst for the selective conversion of glycerol to five-membered dioxolane
Barik, Manas,Chinnaraja, Eswaran,Dabas, Shilpa,Mishra, Jyotiranjan,Subramanian, Palani S.,Subramanian, Saravanan
, p. 695 - 703 (2022/01/22)
The choice of the active site and support matrix decides the activity of a catalyst. Any modifications on these will have a significant impact on the reactivity and selectivity of the catalyst. Here, we have synthesised WO3-loaded boehmite and applied it for the acetalization of a biomass-derived bulk chemical, glycerol. The well-characterized acid catalyst exhibits a selective acetalization of glycerol with good conversions into a five-membered dioxolane product. The cyclability of the catalyst up to six times along with the retention of the catalytic activity ensures the heterogeneity of the material.
SYNTHESIS OF DERIVATIVES OF 1,3-DIOXANE WITH MESOMORPHOUS CHARACTERISTICS
Murza, M. M.,Safarov, M. G.,Nazmukhanova, R. M.
, p. 119 - 120 (2007/10/02)
2-p-Nitrophenyl-1,3-dioxan-5-yl 4-(4-alkoxybenzylideneamino)benzoates were sythesized.They possess the characteristics of smectic and nematic liquid crystals in the range of 90-221 deg C.
