89869-02-3

Basic information

• Product Name: 2-(benzyloxy)-2-cyclohexylacetaldehyde
• Synonyms: 2-(benzyloxy)-2-cyclohexylacetaldehyde
• CAS NO: 89869-02-3
• Molecular Weight: 232.323
• Mol File: 89869-02-3.mol

Chemical Properties

• CAS DataBase Reference: 2-(benzyloxy)-2-cyclohexylacetaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(benzyloxy)-2-cyclohexylacetaldehyde(89869-02-3)
• EPA Substance Registry System: 2-(benzyloxy)-2-cyclohexylacetaldehyde(89869-02-3)

Safety Data

• Hazardous Substances Data: 89869-02-3(Hazardous Substances Data)

Upstream product

• 1450842-91-7 C₁₈H₂₆OS₂ 
• 100-39-0 benzyl bromide 
• 144222-05-9 1-cyclohexyl-1-(benzyloxy)-2-propene 

Downstream Products

• 22733-94-4 benzyl cyclohexanecarboxylate 
• 3085-54-9 N-(4-methylphenyl)formamide 
• 89869-04-5 syn-1-Cyclohexyl-1-benzyloxypent-4-en-2-ol 
• 89869-04-5 anti-1-Cyclohexyl-1-benzyloxypent-4-en-2-ol 
• 110598-79-3 [(R)-1-((R)-Benzyloxy-cyclohexyl-methyl)-allyloxy]-methyl-diphenyl-silane 
• 110598-79-3 [(R)-1-((S)-Benzyloxy-cyclohexyl-methyl)-allyloxy]-methyl-diphenyl-silane 
• 91751-28-9 (1S,2S,3R)-1-Benzyloxy-1-cyclohexyl-3-methyl-pent-4-en-2-ol 
• 91751-28-9 (1S,2S,3S)-1-Benzyloxy-1-cyclohexyl-3-methyl-pent-4-en-2-ol 
• 94499-05-5 S-ethyl 4-(benzyloxy)-4-cyclohexyl-2-butenethioate 

Relevant articles and documents

Aniline mediated oxidative C-C bond cleavage of α-alkoxy aldehydes in air and a model reaction for the synthesis of α-(d)-amino acid derivatives

A metal-free and 4-methyl aniline mediated method for the oxidative C-C bond cleavage has been developed. The reaction proceeds in air using molecular oxygen as the oxidant, affording one-carbon shortened esters in moderate to good yields within a short time. Moreover, it provides a model reaction for the highly enantioselective synthesis of (d)-serine esters by combining with a l-proline catalyzed Mannich reaction.

Super-acid Catalysed Addition of Allylsilanes to Carbonyl Compounds; Synthetic and Mechanistic Aspects

The addition of allyltrimethylsilane 8 to a variety of aldehydes and one ketone (cyclohexanone) was found to be induced by the super-acid TfOH2(1+)B(OTf)4(1-) (Tf = CF3SO2).In contrast to the analogous Lewis acid catalysed reaction, only catalytic amounts