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89870-08-6

((η5-C5(CH3)5)iron(carbonyl)2(tetrahydrofuran))(PF6) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 89870-08-6 Structure

  • Basic information

    1. Product Name: ((η5-C5(CH3)5)iron(carbonyl)2(tetrahydrofuran))(PF6)
    2. Synonyms: ((η5-C5(CH3)5)iron(carbonyl)2(tetrahydrofuran))(PF6)
    3. CAS NO:89870-08-6
    4. Molecular Formula:
    5. Molecular Weight: 464.168
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 89870-08-6.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: ((η5-C5(CH3)5)iron(carbonyl)2(tetrahydrofuran))(PF6)(CAS DataBase Reference)
    10. NIST Chemistry Reference: ((η5-C5(CH3)5)iron(carbonyl)2(tetrahydrofuran))(PF6)(89870-08-6)
    11. EPA Substance Registry System: ((η5-C5(CH3)5)iron(carbonyl)2(tetrahydrofuran))(PF6)(89870-08-6)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 89870-08-6(Hazardous Substances Data)

89870-08-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 89870-08-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,9,8,7 and 0 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 89870-08:
(7*8)+(6*9)+(5*8)+(4*7)+(3*0)+(2*0)+(1*8)=186
186 % 10 = 6
So 89870-08-6 is a valid CAS Registry Number.

89870-08-6Upstream product

89870-08-6Relevant articles and documents

Synthesis and reactivity of the pentamethylcyclopentadienyl iron acetyl complex 5-C5Me5)Fe(CO)(PPh3)COMe>

Barras, Jean-Pierre,Davies, Stephen G.,Metzler, Michael R.,Edwards, Alison J.,Humphreys, Vanessa M.,Prout, Keith

, p. 157 - 166 (1993)

(RS)-5-C5Me5)Fe(CO)(PPh3)COMe> (1) was synthesised from 5-C5Me5)Fe(CO)2>2 (3) in three steps with an overall yield of 28percent.The lithium enolate from 1 was alkylated with methyl iodide and benzyl bromide to give 11 and 12 in 94 and 97percent yields respectively.The corresponding diethylaluminium enolate derived from 1 reacted with high stereoselectivity with benzaldehyde whereas no selectivity was observed with the lithium enolate.A single crystal X-ray structure analysis of (RS)-5-C5Me5)Fe(CO)(PPh3)COCH2CH2Ph> (12) is reported.

OXIDATIVE CLEAVAGE OF THE Fe-Fe BOND IN 2 USING FERROCINIUM ION: A FACILE ROUTE TO THE SYNTHETICALLY USEFUL COMPLEXES +

Catheline, Daniel,Astruc, Didier

, p. C11 - C14 (2007/10/02)

Complexes of the type +PF6-, 3a-3d, (Fp' = (η5-C5Me5)-Fe(CO)2, solvent = THF, CH3COOCH3, CH3CN, or pyridine) are conveniently prepared by the reaction between Fp'2 and Cp2Fe+PF6-, (Cp = η5-C5H5) in the solvent under ambient conditions.The complexes +PF6-, 3e-3g, (L = CO, PPh3, P(OPh)3) are readily prepared from +.Fp'H is formed by treatment of 3a with NaBH4.Fp'SC(S)NMe2 can be prepared from 3a or 3e and NaSC(S)NMe2.

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