89894-04-2Relevant academic research and scientific papers
Structure of the t-butyl N-(4-chlorophenyl)thiooxamate and related complexes with heavy metals
Raouf-Benchekroun, Khadija,Bastide, Jean-Daniel,De Blic, Arnaud,Cazaux, Louis,Baltas, Michel
, p. 191 - 201 (1999)
The structure of the title thiooxamate was studied by molecular modeling and i.r spectroscopy along with its ZnBr2 complex and transformation products, thiooxamic acid and zinc thiooxamates. Similar results were obtained with heavy metal salts like Cd(II) and Hg(II) perchlorates with, moreover, formation constants determination of their complexes by ultra- violet spectrophotometry.
New approach to the synthesis of 2-carbamoylbenzothiazoles
Yarovenko, V. N.,Stoyanovich, F. M.,Zolotarskaya, O. Yu.,Chernoburova, E. I.,Zararzin, I. V.,Krayushkin, M. M.
, p. 144 - 147 (2007/10/03)
The reactions of substituted anilines with chloroacetamide and sulfur in the presence of triethylamine afforded monothiooxamides. When treated with K3Fe(CN)6, the latter underwent cyclization to form 2-carbamoyIbenzothiazoles. The reactions were accompanied by the formation of the corresponding thiooxanilic acids, which also underwent cyclization to form benzothiazole-2-carboxylic acids.
