89902-45-4

Basic information

• Product Name: Silanol, (1,1-dimethylethyl)dimethyl-, 4-methylbenzenesulfonate
• CAS NO: 89902-45-4
• Molecular Formula: C13H22O3SSi
• Molecular Weight: 286.467
• Mol File: 89902-45-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silanol, (1,1-dimethylethyl)dimethyl-, 4-methylbenzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: Silanol, (1,1-dimethylethyl)dimethyl-, 4-methylbenzenesulfonate(89902-45-4)
• EPA Substance Registry System: Silanol, (1,1-dimethylethyl)dimethyl-, 4-methylbenzenesulfonate(89902-45-4)

Safety Data

• Hazardous Substances Data: 89902-45-4(Hazardous Substances Data)

Upstream product

• 103872-45-3 1-(tert-butyldimethylsilyl)-1H-pyrrole 
• 104-15-4 toluene-4-sulfonic acid 
• 16836-95-6 silver(I) 4-methylbenzenesulfonate 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Relevant articles and documents

A Convenient Synthesis of 8-Substituted Indolizines as Precursors to 5-Substituted Cycl{3.2.2}azine Derivatives

The synthesis of 8-substituted indolizines is described via a two step process in which a 1,4-diketone, containing a tert-butyl group, is cyclocondensed with a trialkylsilyl protected pyrrole to provide 5,8-disubstituted indolizines in higher yields than the identical reaction with unprotected pyrrole. Cleavage of the tertbutyl group from the indolizine 5-position, by treatment with 85% phosphoric acid, provides 8-substituted indolizines in good yields. Treatment of 8-substituted indolizines with dimethyl acetylenedicarboxylate, in the presence of palladium-on-carbon, provides novel 5-substituted cycl{3.2.2} derivatives.