89940-12-5Relevant articles and documents
Selective manganese-mediated transformations using the combination: KMnO4/Me3SiCl
Marko, Istvan E.,Richardson, Paul R.,Bailey, Mark,Maguire, Anita R.,Coughlan, Niall
, p. 2339 - 2342 (1997)
A novel manganese reagent, generated from KMnO4 and Me3SiCl, in the presence of a quaternary ammonium salt, is shown to smoothly dichlorinate alkenes, open epoxides and chemoselectively oxidise sulfides to sulfoxides.
Reduction of α-Chlorocarbonyl Compounds by the Tributyltin Hydride-Phosphine Oxide Combined System. Chemoselective Reduction of the Carbonyl Group
Shibata, Ikuya,Suzuki, Taro,Baba, Akio,Matsuda, Haruo
, p. 882 - 883 (2007/10/02)
α-Chlorocarbonyl compounds undergo selective reduction at the carbonyl group with tributyltin hydride-phosphine oxide combined systems to yield chlorohydrins.