Selective manganese-mediated transformations using the combination: KMnO4/Me3SiCl

DOI: 10.1016/S0040-4039(97)00309-2

Source and publish data:

Tetrahedron Letters p. 2339 - 2342 (1997)

Update date:2022-08-04

Topics:

Authors:

Marko, Istvan E.

Richardson, Paul R.

Bailey, Mark

Maguire, Anita R.

Coughlan, Niall

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Article abstract of DOI:10.1016/S0040-4039(97)00309-2

A novel manganese reagent, generated from KMnO₄ and Me₃SiCl, in the presence of a quaternary ammonium salt, is shown to smoothly dichlorinate alkenes, open epoxides and chemoselectively oxidise sulfides to sulfoxides.

Full text of DOI:10.1016/S0040-4039(97)00309-2

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