Tetrahedron Letters p. 2339 - 2342 (1997)
Update date:2022-08-04
Topics:
Marko, Istvan E.
Richardson, Paul R.
Bailey, Mark
Maguire, Anita R.
Coughlan, Niall
A novel manganese reagent, generated from KMnO4 and Me3SiCl, in the presence of a quaternary ammonium salt, is shown to smoothly dichlorinate alkenes, open epoxides and chemoselectively oxidise sulfides to sulfoxides.
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