89941-46-8Relevant academic research and scientific papers
Preparation and reactivity of polyfunctional zinc and copper organometallics bearing sulfur functionalities
Achyutha Rao,Chou, Tso-Sheng,Schipor, Ioana,Knochel, Paul
, p. 2025 - 2043 (2007/10/02)
Iodomethylthiobenzoate 5 and α-chloroalkyl phenyl sulfides 6 were found to insert zinc dust in THF under very mild conditions (10-25°C, 0.5-2 h) leading to zinc α-thioorganometallics. After a transmetallation with CuCN·2 LiCl, the corresponding copper rea
GENERATION OF THIOCARBONYL YLIDES WITH RELEASE OF DISILOXANE FROM BIS(TRIMETHYLSILYLMETHYL) SULFOXIDES
Aono, Masahiro,Hyodo, Chiaki,Terao, Yoshiyasu,Achiwa, Kazuo
, p. 4039 - 4042 (2007/10/02)
A novel and general method for generation of thiocarbonyl ylide by release of disiloxane from bis(trimethylsilylmethyl) sulfoxide (1) has been found.This method was also demonstrated for generation of aliphatic and aromatic thioaldehyde S-methylide.
