899429-34-6Relevant academic research and scientific papers
Asymmetric [1,2] Stevens rearrangement of (S)-N-benzylic proline-derived ammonium salts under biphasic conditions
Tayama, Eiji,Nanbara, Shintaro,Nakai, Takeshi
, p. 478 - 479 (2007/10/03)
The Stevens rearrangement of (S)-N-benzylic proline-derived ammonium salt with cesium hydroxide in 1,2-dichloroethane is shown to proceed with a high degree of the N-to-C chirality transmission to afford the α-substituted proline derivatives in high enantio-purities. Copyright
