89950-76-5Relevant academic research and scientific papers
The glycosyl-aldonolactone approach for the synthesis of β-d-Galf-(1→3)-d-Manp and 3-deoxy-β-d-xylo-hexofuranosyl-(1→3)-d-Manp
Marino, Carla,Chiocconi, Alejandro,Varela, Oscar,De Lederkremer, Rosa M.
, p. 183 - 189 (2007/10/03)
A convenient synthesis of free β-d-Galf-(1→3)-d-Manp (8a) is reported. The disaccharide is present as external unit in the lipopeptidophosphoglycan (LPPG) of Trypanosoma cruzi and internally in the lipophosphoglycan (LPG) of Leishmania. Condensation of 2,
REGIOSELECTIVE ACYLATIONS OF ALDONO-1,4-LACTONES
Gallo, Carola,Jeroncic, Lucio O.,Varela, Oscar,Lederkremer, Rosa M. de
, p. 841 - 852 (2007/10/02)
Partial benzoylation or pivaloylation of D-gulono-1,4-lactone (1) with 3.3-3.6 molar equivalents of the acyl chloride afforded 2,5,6-tri-O-benzoyl- (3) or 2,5,6-tri-O-pivaloyl-D-gulono-1,4-lactone (5), which were isolated crystalline from the reaction mix
