89954-44-9Relevant academic research and scientific papers
Contributions to the Chemistry of Boron, 134. Adducts of (Dimethylamino)boranes with Aluminium and Gallium Halides
Anton, Klaus,Konrad, Peter,Noeth, Heinrich
, p. 863 - 874 (2007/10/02)
The (dimethylamino)boranes (CH3)2BN(CH3)2 (1) and RB2 (2, 3) form 1:1 adducts 1a-c and 2a, b, 3a, b with AlCl3, AlBr3, and GaCl3, respectively, in contrast to B3 (4) which reacts with GaCl3 to produce a 1:2 adduct 4a.NMR and IR data are in accord with the presence of a simple N-Al or N-Ga coordinative bond for the first two classes of compounds.However, 4a is to be regarded as a tris(dimethylamino)borane-dichlorogallium(1+)tetrachlorogallate containing a bidentate aminoborane component.
