89965-54-8Relevant academic research and scientific papers
Total Synthesis of the Proposed Structure of Mycobactin J
Ghosh, Chiranjit,Pal, Sujit,Patel, Akanksha,Kapur, Manmohan
supporting information, p. 6511 - 6515 (2018/10/20)
The total synthesis of the proposed structure of mycobactin J (MJ), a metabolite of Mycobacterium tuberculosis, is presented. The highlights of the synthesis include a careful control of the Z-stereochemistry of the unsaturated long chain fatty acid, a biomimetic construction of the oxazoline building block and the carriage of an unprotected phenol throughout the synthesis.
A latent oxazoline electrophile for N-O-C bond formation in pseudomonine biosynthesis
Sattely, Elizabeth S.,Walsh, Christopher T.
supporting information; body text, p. 12282 - 12284 (2009/02/05)
Nitrogen-heteroatom bonds figure prominently in the structural, chemical, and functional diversity of natural products. In the case of Pseudomonas siderophore pseudomonine, an N-O hydroxamate linkage is found uncommonly configured in an isoxazolidinone ri
Dehydrative cyclization catalyzed by the combination of molybdenum(VI) oxides and benzoic acids: First synthesis of the antitumour substance BE-70016
Sakakura, Akira,Umemura, Shuhei,Kondo, Rei,Ishihara, Kazuaki
, p. 551 - 555 (2008/02/08)
The dehydrative cyclization of N-(o-hydroxybenzoyl)threonine derivative la is efficiently promoted by the combined use of molybdenum(VI) oxides and benzoic acids bearing electron-with-drawing substituents. In the presence of ammonium molybdate [(NH4
Total Synthesis of Parabactin, a Spermidine Siderophore
Nagao, Yoshimitsu,Miyasaka, Tadayo,Hagiwara, Yuichi,Fujita, Eiichi
, p. 183 - 187 (2007/10/02)
The stereoselective total synthesis of parabactin (1) has been efficiently carried out using substituted 1,3-thiazolidine-2-thione as a leaving group.
