89970-57-0

Upstream product

• 18583-54-5 (2,6-dichlorobenzyl)triphenylphosphonium chloride 
• 99668-08-3 (E)-3-(2,6-dichlorophenyl)acrylaldehyde 
• 83-38-5 2,6-dichlorobenzaldehyde 
• 2014-83-7 1,3-Dichloro-2-chloromethyl-benzene 

Downstream Products

• 89970-53-6 R*,R*-3,4-dichloro-(E)-1-phenyl-4-(2,6-dichlorophenyl)-1-butene 
• 89970-54-7 R*,R*S*,R*-1,2,3,4-tetrachloro-1-phenyl-4-(2,6-dichlorophenyl)-1-butane 
• 90281-06-4 t-2-<(E)-2'-(2,6-dichlorophenyl)ethen-1'-yl>-r-3-(2,6-dichlorophenyl)oxirane 
• 89995-20-0 R*,S*-3,4-dichloro-(E)-1,4-bis-(2,6-dichlorophenyl)-1-butene 
• 89970-58-1 1,4-dichloro-1,4-bis-(2,6-dichlorophenyl)-(E)-2-butene 
• 90281-08-6 threo-t-2-<1',1'-dichloro-t-3'-(2,6-dichlorophenyl)-cycloprop-r-2'-yl>-r-3-(2,6-dichlorophenyl)oxirane 
• 90281-07-5 meso-2,2'-bi(t,t-3,3'-bis(2,6-dichlorophenyl))oxiranyl 
• 90281-05-3 1,1-dichloro-t-2-<(E)-2'-(2,6-dichlorophenyl)ethen-1'-yl>-r-3-(2,6-dichlorophenyl)-cyclopropan 

Relevant academic research and scientific papers

STEREOCHEMISTRY OF BIS-(DICHLOROCYCLOPROPANATION) AND -(EPOXIDATION) OF 1,4-DIARYLBUTADIENES

Dichlorocyclopropanation as well as epoxidation of the 1,4-diarylbutadienes 1-4 to give the mon- and/or bis-adducts according to several methods were studied.Dichlorocyclopropanation is more affected than epoxidation by sterical hindrance of large substituents as 2,6-dichlorophenyl.The bis-adducts are formed preferably as meso- (or threo-) isomers.