89974-39-0Relevant academic research and scientific papers
Addition de Carbanions α Benchrotreniques sur Divers Aldehydes non Enolisables; Evolution des Produits Primaires d'Addition par Oxidation d'Oppenauer-Woodward, influence de la Substitution
Senechal-Tocquer, M. C.,Senechal, D.,Bihan, J. Y. Le,Gentric, D.,Caro, B.
, p. 353 - 364 (2007/10/02)
Aromatic hydrocarbons complexed with a Cr(CO)3 unit react with benzaldehydes and furfural in THF and in presence of t-BuOK at the benzylic position to give condensation products in good yields.Formation of ketones by in situ Oppenauer-Woodward oxidation is observed.Influence of ring substituents on this formation is discussed.
Elaboration of α-Substituted Benzyl Ethers and Sulphides by Suppression of the Wittig and Related Rearrangements
Davies, Stephen G.,Holman, Nicholas J.,Laughton, Charles A.,Mobbs, Bryan E.
, p. 1316 - 1317 (2007/10/02)
Co-ordination of benzyl alkyl ethers and sulphides to chromium tricarbonyl allows α-substitution via the corresponding α-carbanions to be achieved by suppression of the Wittig and related rearrangements.
