899794-49-1

Basic information

• Product Name: dithiocarbonic acid S-[5,5-dimethyl-4-oxo-1-(2-phenyl[1,3]dioxolan-2-yl)hexyl] ester O-ethyl ester
• Synonyms: dithiocarbonic acid S-[5,5-dimethyl-4-oxo-1-(2-phenyl[1,3]dioxolan-2-yl)hexyl] ester O-ethyl ester
• CAS NO: 899794-49-1
• Molecular Weight: 396.572
• Mol File: 899794-49-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dithiocarbonic acid S-[5,5-dimethyl-4-oxo-1-(2-phenyl[1,3]dioxolan-2-yl)hexyl] ester O-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: dithiocarbonic acid S-[5,5-dimethyl-4-oxo-1-(2-phenyl[1,3]dioxolan-2-yl)hexyl] ester O-ethyl ester(899794-49-1)
• EPA Substance Registry System: dithiocarbonic acid S-[5,5-dimethyl-4-oxo-1-(2-phenyl[1,3]dioxolan-2-yl)hexyl] ester O-ethyl ester(899794-49-1)

Safety Data

• Hazardous Substances Data: 899794-49-1(Hazardous Substances Data)

Upstream product

• 29568-66-9 2-phenyl-2-vinyl-[1,3]dioxolane 
• 82721-84-4 O-ethyl S-(3,3-dimethyl-2-oxo-butyl) dithiocarbonate 

Downstream Products

• 540741-14-8 dithiocarbonic acid S-[3-benzoyl-1-(2-ethyl-[1,3]dioxolan-2-yl)-7,7-dimethyl-6-oxooctyl] ester O-ethyl ester 
• 540741-15-9 2-[2-(2-ethyl-[1,3]dioxolan-2-yl)ethyl]-6,6-dimethyl-1-phenylheptane-1,5-dione 
• 111183-85-8 6,6-dimethyl-1-phenylheptane-1,5-dione 
• 59321-55-0 2-(tert-butyl)-6-phenylpyridine 
• 899794-58-2 dithiocarbonic acid S-(1-benzoyl-5,5-dimethyl-4-oxohexyl) ester O-ethyl ester 
• 540741-19-3 2,2-dimethyl-6-(2-phenyl-[1,3]dioxolan-2-yl)hexan-3-one 

Relevant articles and documents

An expedient, flexible and convergent access to selectively protected 1,5-dicarbonyl compounds. Applications to the synthesis of 2,6-disubstituted pyridines and thiopyridines

Intermolecular addition of 2-oxoalkyl radicals generated from the corresponding S-alkyl-O-ethyl dithiocarbonates on vinyl ketals afforded selectively protected 1,5-dicarbonyl compounds in good yields. These key-intermediates can be converted into a plethora of useful substances. Transformations to pyridines and thiopyridines were given as examples. Georg Thieme Verlag Stuttgart.