111183-85-8Relevant articles and documents
An expedient, flexible and convergent access to selectively protected 1,5-dicarbonyl compounds. Applications to the synthesis of 2,6-disubstituted pyridines and thiopyridines
Boivin, Jean,Carpentier, Floriane,Jrad, Rafik
, p. 1664 - 1672 (2007/10/03)
Intermolecular addition of 2-oxoalkyl radicals generated from the corresponding S-alkyl-O-ethyl dithiocarbonates on vinyl ketals afforded selectively protected 1,5-dicarbonyl compounds in good yields. These key-intermediates can be converted into a plethora of useful substances. Transformations to pyridines and thiopyridines were given as examples. Georg Thieme Verlag Stuttgart.
Enaminone Intermediate in the One-Methylene Incorporated Dimerization Reaction of Ketone Enolate. Cross Reaction to Unsymmetrical 1,5-Diketones
Kiyooka, Syun-ichi,Yamashita, Tsuneo
, p. 1775 - 1778 (2007/10/02)
An enaminone has been isolated as an intermediate from the one-methylene incorporated dimerization reaction of ketone enolate using N-phenyl-N-methylformamide.The reaction of the enaminone with the other ketone enolates gives unsymmetrical 1,5-diketones i