89997-06-8Relevant academic research and scientific papers
Fulvalene Ylides. A Stevens Rearrangement of 1-Fluoren-9-ylidene-1,2,5-triphenyl-λ5-phosphole
Gilheany, Declan G.,Kennedy, Deirdre A.,Malone, John F.,Walker, Brian J.
, p. 1217 - 1218 (1984)
Quantitative, thermal rearrangement of the title ylide provides the first authentic example of a 1,2-Stevens rearrangement of a phosphorus ylide; the structure of the spiro-1,2-dihydrophosphorinine product has been confirmed by X-ray analysis.
YLIDE ANALOGUES OF FULVALENES. A STEVENS REARRANGEMENT OF A PHOSPHONIUM YLIDE.
Gilheany, Declan G.,Walker, Brian J.
, p. 183 - 186 (2007/10/02)
Fulvalene-ylides have been synthesised.The pentafulvalene ylide analogue (8) provides the first Stevens rearrangement of a phosphonium ylide and, through reaction with DMAD, a novel 1-phosphabicyclooctratriene ylide.
