Fulvalene Ylides. A Stevens Rearrangement of 1-Fluoren-9-ylidene-1,2,5-triphenyl-λ5-phosphole

DOI: 10.1039/c39840001217

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1217 - 1218 (1984)

Update date:2022-08-16

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Authors:

Gilheany, Declan G.

Kennedy, Deirdre A.

Malone, John F.

Walker, Brian J.

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Article abstract of DOI:10.1039/c39840001217

Quantitative, thermal rearrangement of the title ylide provides the first authentic example of a 1,2-Stevens rearrangement of a phosphorus ylide; the structure of the spiro-1,2-dihydrophosphorinine product has been confirmed by X-ray analysis.

Full text of DOI:10.1039/c39840001217

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