Fulvalene Ylides. A Stevens Rearrangement of 1-Fluoren-9-ylidene-1,2,5-triphenyl-λ5-phosphole

DOI: 10.1039/c39840001217

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1217 - 1218 (1984)

Update date:2022-08-16

Topics:

Authors:

Gilheany, Declan G.

Kennedy, Deirdre A.

Malone, John F.

Walker, Brian J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840001217

Quantitative, thermal rearrangement of the title ylide provides the first authentic example of a 1,2-Stevens rearrangement of a phosphorus ylide; the structure of the spiro-1,2-dihydrophosphorinine product has been confirmed by X-ray analysis.

Full text of DOI:10.1039/c39840001217

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₃₅H₂₅P

Cas No:89997-06-8

R&D Labs maybe for 89997-06-8

SINO Industries Company Limited(expird)

Contact:86-29-85369724

Address:No.111, Jiefang Road, Xi’an, China
TAIZHOU XINGCHENG CHEMPHARM CO.,LTD.

Contact:0086-0576-88551200,88886292 ,88880039

Address:B Area. 10 Floor.Yaodadasha. 289#.Shifu Road.Taizhou.Zhejiang.China
Wuhan Shengmao Corp

website:http://www.shengmaochem.com

Contact:86-27-82853423, 82819281

Address:Rm 202, A Unit Huaqiao Building No. 2, Lihuangpi Road, Wuhan, China
Xiamen Yunfan Biotech Co., Ltd.

Contact:0592-7828678-#

Address:Xiamen
SEA BRGIHT INDUSTRY CO.,LIMITED

Contact:0086 755 8622 3990

Address:Rm 17B3,GuangCaiXinTianDi Bldg,GuiMiao Rd,NanShan District,Shenzhen,China

Relevant to this article

Titanium salan catalysts for the asymmetric epoxidation of alkenes: Steric and electronic factors governing the activity and enantioselectivity

Doi:10.1002/chem.201404157
(2014)
Doi:10.1021/ja00984a036
(1967)
Synthetic Routes toward Acidic Pentasaccharide Related to the O-Antigen of E. coli 120 Using One-Pot Sequential Glycosylation Reactions

Doi:10.1021/acs.joc.7b00561
(2017)
Design, synthesis, and structure-activity relationships of novel 2-substituted pyrazinoylguanidine epithelial sodium channel blockers: Drugs for cystic fibrosis and chronic bronchitis

Doi:10.1021/jm051134w
(2006)
The Photochemistry of 2,3-Bis(p-methoxyphenyl)oxirane: Trapping of a C-C Cleaved Intermediate in an Electron-transfer Sensitised Process

Doi:10.1039/c39840000134
(1984)
Construction of enantiomerically enriched tertiary α- hydroxycarboxylic acid derivatives by phase-transfer-catalyzed asymmetric alkylation of diaryloxazolidin-2,4-diones

Doi:10.1002/anie.200600470
(2006)

Article Doi