Fulvalene Ylides. A Stevens Rearrangement of 1-Fluoren-9-ylidene-1,2,5-triphenyl-λ5-phosphole

DOI: 10.1039/c39840001217

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1217 - 1218 (1984)

Update date:2022-08-16

Topics:

Authors:

Gilheany, Declan G.

Kennedy, Deirdre A.

Malone, John F.

Walker, Brian J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840001217

Quantitative, thermal rearrangement of the title ylide provides the first authentic example of a 1,2-Stevens rearrangement of a phosphorus ylide; the structure of the spiro-1,2-dihydrophosphorinine product has been confirmed by X-ray analysis.

Full text of DOI:10.1039/c39840001217

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₃₅H₂₅P

Cas No:89997-06-8

R&D Labs maybe for 89997-06-8

Jiangsu Fengshan Group Co., Ltd.

Contact:86-25-86558671

Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China
Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone
Shanghai Gsyn Chemical Co.,Ltd.

Contact:86-021-67158290

Address:86-021-67158291
Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China

Relevant to this article

Titanium salan catalysts for the asymmetric epoxidation of alkenes: Steric and electronic factors governing the activity and enantioselectivity

Doi:10.1002/chem.201404157
(2014)
Doi:10.1021/ja00984a036
(1967)
Synthetic Routes toward Acidic Pentasaccharide Related to the O-Antigen of E. coli 120 Using One-Pot Sequential Glycosylation Reactions

Doi:10.1021/acs.joc.7b00561
(2017)
Design, synthesis, and structure-activity relationships of novel 2-substituted pyrazinoylguanidine epithelial sodium channel blockers: Drugs for cystic fibrosis and chronic bronchitis

Doi:10.1021/jm051134w
(2006)
The Photochemistry of 2,3-Bis(p-methoxyphenyl)oxirane: Trapping of a C-C Cleaved Intermediate in an Electron-transfer Sensitised Process

Doi:10.1039/c39840000134
(1984)
Construction of enantiomerically enriched tertiary α- hydroxycarboxylic acid derivatives by phase-transfer-catalyzed asymmetric alkylation of diaryloxazolidin-2,4-diones

Doi:10.1002/anie.200600470
(2006)

Article Doi