90001-43-7Relevant articles and documents
Synthesis of highly fluorescent and soluble 1,2,4-linking hyperbranched poly(arylenevinylene) featuring intramolecular energy funneling
Xie, Zengqi,Yoon, Seong-Jun,Park, Soo Young
, p. 1638 - 1644 (2010)
The synthesis and optical properties of a highly soluble (>200mg mL -1) and highly fluorescent (ΦF in film =0.64) 1,2,4-linking hyperbranched poly(arylenevinylene) (1,2,4-hb-PAV) prepared via Wittig reaction of A3 (bipheny
Interfacially synthesized 2D COF thin film photocatalyst: efficient photocatalyst for solar formic acid production from CO2and fine chemical synthesis
Yadav, Dolly,Kumar, Abhishek,Kim, Jae Young,Park, No-Joong,Baeg, Jin-Ook
supporting information, p. 9573 - 9580 (2021/04/26)
The targeted synthesis of an efficient, visible light active, recyclable, freestanding covalent organic framework thin film photocatalyst for multi-faceted photocatalysis is the essence of the proposed work. A simple, scalable, reagent free synthesis of a thin film at the interface of 5,10,15,20-tetra-(4-aminophenyl)porphyrin, 2-vinylbenzene-1,4-dicarbaldehyde in nitrobenzene and aqueous glyoxal affords centimetre sized continuous 2D thin film with substantial stability, flexibility and efficient visible light activity. Strikingly different from the regular imine based COF, the incorporation of the glyoxal unit as a modulator helps in band gap tuning and induces flexibility within the thin film. An interplay between time and concentration helps in achieving a thin film photocatalyst with efficient photocatalytic activity for 1,4-NADH regeneration and selective formic acid formation from CO2. The optimum band edge position of the thin film photocatalyst also enables solar fine chemical synthesisviareductive dehalogenation under visible light illumination with excellent recyclability. The present work gives insight into visible light active thin film formation en route to metal-free sustainable photocatalysis.
Synthesis and Electrochemical Properties of 2,5-Disubstituted 1,4-Bis(4,5-diphenyl-1H-imidazol-2-yl)benzene Derivatives
Chugunov, D. B.,Klimaeva, L. A.,Okina, E. V.,Selivanova, Yu. M.,Timonina, A. S.
, p. 1222 - 1227 (2020/10/02)
Abstract: 2,5-Disubstituted 1,4-bis(4,5-diphenyl-1H-imidazol-2-yl)benzenes have been synthesized, and their electrochemical properties have been studied by cyclic voltammetry, in particular the effect of substituents on the redox characteristics has been examined. The reversible electrochemical redox transformation quinone–biradical of the title compounds occurs at positive potentials.