90018-66-9Relevant academic research and scientific papers
Highly diastereoselective condensation of α-nitro-esters with aldehydes catalyzed by zinc complexes of amino acids
Chatterjee,Jha,Joshi
, p. 5287 - 5289 (2007/10/03)
Zinc complexes of amino acids efficiently catalyze the condensation between α-nitro-esters and a variety of aldehydes. An unusual domino reaction sequence leads to the diastereoselective formation of substituted isoxazoline N-oxides in high yields.
A Convenient One-Pot Synthesis of 4-Substituted 3,5-Bis(alkoxycarbonyl)-4,5-dihydroisoxazole 2-Oxides from Aldehydes and Nitroacetic Esters in a Solid-Liquid Reaction System and Subsequent Deoxygenation
Melot, Jean-Marie,Texier-Boullet, Francoise,Foucaud, Andre
, p. 558 - 560 (2007/10/02)
4-Substituted 3,5-bis(alkoxycarbonyl)-4,5-dihydroisoxazole 2-oxides are obtained from nitroacetic esters and imines which are prepared from aldehydes and isopropylamine in the presence of molecular sieves.Reduction of the N-oxides with trimethyl phosphite
