90030-13-0Relevant academic research and scientific papers
Templated synthesis of interlocked macrocyclic ligands, the catenands. Preparation and characterization of the prototypical bis-30 membered ring system
Dietrich-Buchecker, Christiane,Sauvage, Jean-Pierre
, p. 503 - 512 (1990)
We describe here the detailed template synthesis of a copper(I) catenate. Demetallation leads to the corresponding free ligand, a catenand. Both molecules are made of two interlocked 30 membered rings.
SYNTHESE DE COMPOSES POLYETHERS MACROCYCLIQUES DERIVES DE LA PHENANTHROLINE-1,10 DIPHENY<-2,9.
Dietrich-Buchecker C. O.,Sauvage, J. P.
, p. 5091 - 5094 (2007/10/02)
The macrocyclic compound (V) and (VI) have been synthesized in three steps from phenenthroline, with an overall yield of 35percent.These new ligands contain two coordination sites whose electronic properties are drastically different: the phenanthroline subunit and the polyoxyethylene chain; the latter prevents ligands (V) or (VI) from forming analogues of bis-phenanthroline complexes of transition metals.
