90036-65-0

Upstream product

• 23974-72-3 sodium phenylselenide 
• 107574-36-7 (2E)-hex-2-en-1-yl methyl carbonate 
• 190662-66-9 1-methylseleno-2-hexene 
• 4798-44-1 1-hexene-3-ol 
• 645-96-5 Benzeneselenol 
• 2497-18-9 (E)-2-hexen-1-yl acetate 
• 1666-13-3 diphenyl diselenide 

Downstream Products

• 91230-11-4 (1-vinyl-butyl)-carbamic acid benzyl ester 
• 4798-44-1 1-hexene-3-ol 
• 104937-85-1 (±)-N-benzylhex-1-en-3-amine 
• 1666-13-3 diphenyl diselenide 

Relevant academic research and scientific papers

Iridium-catalyzed allylic alkylations of sodium phenyl selenide

An iridium-catalyzed allylic substitution of sodium phenyl selenide with unsymmetrical allyl carbonates was accomplished, which produced the linear allyl phenyl selenides in 38%-74% yields. An asymmetric iridium-catalyzed allylation of sodium phenyl selen

Oxidation of allylselenides with the sharpless AD-reagents

Allylselenides are efficiently oxidized by AD-mix reagents. Oxidation takes chemoselectively place on the selenium atom of allylselenides bearing a methylseleno or a phenylseleno moiety, but chemoselectively occurs on the C,C double bond of the corresponding o-nitrophenyl derivatives.

Samarium(II) Di-iodide Induced Synthesis of Allylic Phenyl Selenides from Allylic Acetates and Diphenyl Diselenide in the Presence of Palladium Catalyst

Allylic phenyl selenides are prepared efficiently from the reaction of allylic acetates and diphenyl diselenide induced by samarium(II) diiodide in the presence of a palladium catalyst under mild conditions.

SYNTHESIS OF PROTECTED ALLYLIC AMINES FROM ALLYLIC PHENYL SELENIDES: IMPROVED CONDITIONS FOR THE CHLORAMINE T OXIDATION OF ALLYLIC PHENYL SELENIDES

Anhydrous chloramine T in methanol is a highly effective reagent for the conversion of allylic phenyl selenides to the corresponding rearranged N-allylic-p-toluenesulfonamides.The reaction presumably proceeds via an allylic selenimide intermediate which undergoes -sigmatropic rearrangement.