90054-88-9Relevant articles and documents
A Method for the Preparation of β-Amino-α,β-unsaturated Carbonyl Compounds: Study of Solvent Effect and Mechanism
R. S., Reyno,Sugunan, Akash,S., Ranganayakulu,Suresh, Cherumuttathu H.,Rajendar, Goreti
supporting information, p. 1040 - 1045 (2020/02/15)
An efficient method for the preparation of β-amino-α,β-unsaturated carbonyl compounds is demonstrated. Bench-stable sodium 3-oxo-enolates were prepared from carbonyl compounds, and reacted with amines in the presence of an acid and a desiccant. DFT studie
Methyl β-(benzotriazol-1-yl)vinyl ketone: A new β-acetylvinyl cation equivalent
Katritzky, Alan R.,Blitzke, Torsten,Li, Jianqing
, p. 3773 - 3781 (2007/10/03)
A simple and efficient two-step approach to methyl β-(benzotriazol-1-yl)vinyl ketone 7 is described. The synthetic utility of compound 7 has been demonstrated by nucleophilic substitutions of the benzotriazolyl group with a range of nucleophiles. Thus, me
Protonation and Acylation Reactions of Acyclic Enamino Ketones
Boehme, Horst,Traenka, Manfred
, p. 149 - 159 (2007/10/02)
α,β-Unsaturated β-dialkylamino ketones 4 are converted by means of tetrafluoroboric acid into thermodynamically stable Cα-protonated iminium salts 5. β-(Dialkylamino)vinyl ketones are shown to exist preferentially in the E-s-cis and E-s-trans c
