31172-37-9Relevant academic research and scientific papers
1-ETHOXYCARBONYLQUINOLIZINIUM SALTS CONDENSATION OF β-KETOENOL ETHERS WITH 2-PYRIDYLACETATES
Szychowski, Jerzy,Leniewski, Andrzej,Wrobel, Jerzy T.,Glinka, Tomasz
, p. 1072 - 1080 (1992)
A general route to some 1-ethoxycarbonylquinolizinium bromides has been worked out.The method allow to conduct the condensation between β-ketoenol ethers and substituted 2-pyridylacetates in homogenous conditions in the presence of trifluoroacetic acid in an aprotic solvent.The substitution at C-6 in 2-pyridylacetates completely changes the reaction course affording 3,6-disubstituted 2-pyrones.
