900783-38-2

Upstream product

• 4541-14-4 4-benzyloxy-butan-1-ol 
• 100-39-0 benzyl bromide 
• 5470-84-8 4-benzyloxybutanal 
• 900783-30-4 1-[4-benzyl-2-oxo-(4S)-1,3-oxazolan-3-yl]-6-benzyloxy-3-hydroxy-2-(4-methoxybenzyloxy)-(2S,3R)-hexan-1-one 
• 900783-36-0 1-(3-benzyloxypropyl)-2-(4-methoxybenzyloxy)-(1R,2R)-3-butenyl alcohol 
• 900783-35-9 6-benzyloxy-3-hydroxy-2-(4-methoxybenzyloxy)-(2S,3R)-hexanal 
• 900783-37-1 7-benzyloxy-(3R,4R)-1-heptene-3,4-diol 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 675127-26-1 1-[1-benzyloxy-(1S)-heptyl]-(1S)-3-butenyl 3-[2,2-dimethyl-5-vinyl-(4R,5R)-1,3-dioxolan-4-yl]propanoate 
• 675127-27-2 (5R,6R,7E,10S)-10-[(1'S)-1'-benzyloxyheptyl]-5,6-isopropylidenedioxy-3,4,5,6,9,10-hexahydro-2H-oxecin-2-one 

Relevant academic research and scientific papers

Stereoselective total synthesis of microcarpalide

A stereoselective total synthesis of microcarpalide using ring-closing metathesis (RCM) as a key step is reported. l-Ascorbic acid was used as a chiral pool material for the construction of the olefinic alcohol and an asymmetric aldol reaction provided the chiral precursor for the synthesis of olefinic acid.