900792-05-4Relevant academic research and scientific papers
Chemoenzymatic synthesis of the trans-dihydrodiol isomers of monosubstituted benzenes via anti-benzene dioxides
Boyd, Derek R.,Sharma, Narain D.,Llamas, Nuria M.,O'Dowd, Colin R.,Allen, Christopher C. R.
, p. 2208 - 2217 (2008/02/09)
Enantiopure cis-2,3-dihydrodiols, available from dioxygenase-catalysed cis-dihydroxylation of monosubstituted benzene substrates, have been used as synthetic precursors of the corresponding trans-3,4-dihydrodiols. The six-step chemoenzymatic route from ci
Chemoenzymatic synthesis of carbasugars from iodobenzene
Boyd, Derek R.,Sharma, Narain D.,Llamas, Nuria M.,Malone, John F.,O'Dowd, Colin R.,Allen, Christopher C. R.
, p. 1953 - 1963 (2007/10/03)
The versatile enantiopure cis-dihydrodiol metabolite 1, formed by bacterial metabolism of iodobenzene, has been used for the synthesis of the pyranose carbasugars (pseudosugars) carba-β-D-altropyranose 2, carba-α-L- galactopyranose 3, carba-β-D-idopyranos
Enantiopure arene dioxides: Chemoenzymatic synthesis and application in the production of trans-3,4-dihydrodiols
Boyd,Sharma,O'Dowd,Hempenstall
, p. 2151 - 2152 (2007/10/03)
Enantiopure syn- and anti-arene dioxides are synthesised from cis-dihydrodiol metabolites; anti-benzene dioxides are reduced to enantiopure trans-3,4-dihydrodiols while synbenzene dioxides racemise thermally via 1,4-dioxocins.
