90083-95-7Relevant academic research and scientific papers
Metal-Catalyzed Stereospecific Michael Reaction Equivalent
Godleski, Stephen A.,Villhauer, Edwin B.
, p. 2246 - 2252 (2007/10/02)
The addition of nucleophiles to vinyl sulfide-allylic acetates mediated by (?-allyl)palladium intermediates has been shown to occur exclusively on the allyl terminus remote from sulfur, thereby effecting the equivalent to a Michael reaction.Due to the int
A NEW APPROACH TO REGIOCONTROLLED ENONE TRANSPOSITIONS BASED ON THE FACILE CONVERSION OF α,β-ENONE TOSYLHYDRAZONES TO THE TRANSPOSED ALLYLIC SULFIDES
Mimura, Tetsuya,Nakai, Takeshi
, p. 1579 - 1582 (2007/10/02)
A new, facile method for the conversion of α,β-enone tosylhydrazones to the transposed allylic sulfides is described which combines sulfenylation of the hydrazone dianions with hydride reduction of the α'-sulfenylated hydrazones.This novel route to allyli
