90101-28-3Relevant academic research and scientific papers
Silyl isothiocyanates
-
, (2008/06/13)
The invention concerns novel compounds of formula IIIA wherein Ra is selected from electron donating substituents consisting of alkoxy of 1-10 carbon atoms, cycloalkoxy of 4-8 carbon atoms, aralkoxy of 7-12 carbon atoms, phenoxy which may b
5,6,7,8-Tetrahydroquinolines. Part 6. Silylation vs. Thioamidation in the Reaction of Silyl Isothiocyanates with Organometallics: Influence of the Solvent and of the Substituent on Silicon.
Crossley, Roger,Shepherd, Robin G.
, p. 1917 - 1920 (2007/10/02)
The influence of a number of variables on carbophilic vs. silicophilic attack by 8-lithio-3-methyl-5,6,7,8-tetrahydroquinoline on silyl isothiocyanates is reported.In general carbophilic attack (i.e. thiomidation) is favoured in solvents of low polarity a
