90163-00-1Relevant academic research and scientific papers
Microwave-assisted benzyl mono- and dibromination in diethyl carbonate as environmentally friendly alternative to radical bromination in carbon tetrachloride
Pingali, Subramanya R. K.,Upadhyay, Sunil K.,Jursic, Branko S
experimental part, p. 928 - 933 (2011/05/15)
An environmentally friendly benzyl mono- and di-bromination synthetic procedure was developed that is superior to the classic carbon tetrachloride bromination procedure in both reaction time and isolated yield. This new reaction was performed in diethyl carbonate as reaction media using microwave instead of conventional heating. Both the solvent and the brominating reagent N-bromosuccinimide (prepared from succinimide obtained from the reaction mixture) are recyclable. Practically, the preparation of our target compounds was completed in less than two hours. The Royal Society of Chemistry.
A simple key for benzylic mono- and gem-dibromination of primary aromatic amine derivatives using molecular bromine1
Kar, Anirban,Argade, Narshinha P.
, p. 221 - 224 (2007/10/03)
Quantitative benzylic mono- and gem-dibromination on primary aromatic amine derivatives have been achieved using molecular bromine and by protecting the amino group as a succinimide moiety. The reactions of N-(o/m/p-tolyl)succinimides 5a-c with 1.25 equiv
