26709-65-9Relevant articles and documents
Photocatalytic Synthesis of Polycyclic Indolones
Saget, Tanguy,K?nig, Burkhard
, p. 7004 - 7007 (2020)
In this work, a photocatalytic strategy for a rapid and modular access to polycyclic indolones starting from readily available indoles is reported. This strategy relies on the use of redox-active esters in combination with an iridium-based photocatalyst under visible-light irradiation. The generation of alkyl radicals through decarboxylative single electron reductions enables intramolecular homolytic aromatic substitutions with a pending indole moiety to afford pyrrolo- and pyridoindolone derivatives under mild conditions. Furthermore, it was demonstrated that these radicals could also be engaged into cascades consisting of an intermolecular Giese-type addition followed by an intramolecular homolytic aromatic substitution to rapidly assemble valuable azepinoindolones.
1, 2, 3, 9-tetrahydro-4H-carbazol-4-one and 8, 9-dihydropyrido- [1, 2-a]indol-6(7H)-one from 1H-indole-2-butanoic acid
Bunce, Richard A.,Nammalwar, Baskar
experimental part, p. 172 - 177 (2009/07/17)
Efficient syntheses of the title ring systems have been developed from 1H-indole-2-butanoic acid, which was easily prepared from 2-fluoro-1- nitrobenzene in four steps. Heating 1H-indole-2-butanoic acid in toluene containing p-toluenesulfonic acid at 110°
SYNTHESIS OF PYRROLOQUINOLINE AND PYRROLONAPHTHYRIDINE BY AN INTRAMOLECULAR CYCLISATION REACTION
Cardinaud, Isabelle,Gueiffier, Alain,Debouzy, Jean-Claude,Milhavet, Jean-Claude,Chapat, Jean-Pierre
, p. 2513 - 2522 (2007/10/02)
4-methylthiopyrrolonaphthyridine and pyrroloquinoline were prepared by an intramolecular cyclisation in acidic media of 1-methylsulfinyl-1-methylthio-2-ethylene.