90173-08-3

Upstream product

• 67-56-1 methanol 
• 90172-83-1 1-Diazo-3-methyl-4-phenyl-pent-4-en-2-one 
• 1445-45-0 Trimethyl orthoacetate 
• 6249-81-6 3-phenyl-but-3-en-2-ol 
• 1035799-84-8 2-Methyl-3-phenyl-but-3-enoyl chloride 
• 90173-14-1 2-methyl-3-phenylbut-3-enoic acid 

Downstream Products

• 1420480-10-9 (Z)-4-phenylhex-4-en-1-ol 
• 1420480-27-8 C₁₃H₁₈O₃S 
• 1420480-45-0 (E)-3-nitro-N-(4-phenylhex-4-en-1-yl)benzenesulfonamide 
• 1420479-57-7 (S)-2-((S)-1-bromoethyl)-1-((3-nitrophenyl)sulfonyl)-2-phenylpyrrolidine 
• 1420479-75-9 (2R,3R)-2-methyl-1-((3-nitrophenyl)sulfonyl)-3-phenylpiperidin-3-ol 
• 1420479-76-0 (R)-6-methyl-1-((3-nitrophenyl)sulfonyl)-5-phenyl-1,2,3,6-tetrahydropyridine 
• 1420479-36-2 (Z)-3-nitro-N-(4-phenylhex-4-en-1-yl)benzenesulfonamide 

Relevant academic research and scientific papers

C2-symmetric cyclic selenium-catalyzed enantioselective bromoaminocyclization

A catalytic asymmetric bromocyclization of trisubstituted olefinic amides that uses a C2-symmetric mannitol-derived cyclic selenium catalyst and a stoichiometric amount of N-bromophthalimide is reported. The resulting enantioenriched pyrrolidine products, which contain two stereogenic centers, can undergo rearrangement to yield 2,3-disubstituted piperidines with excellent diastereoselectivity and enantiospecificity.

Vinylogous Wolff Rearrangement. 4. General Reaction of β,γ-Unsaturated α'-Diazo Ketones

The preparation and vinylogous Wolff rearrangement (VWR) of some 21 acyclic and monocyclic β,γ-unsaturated α'-diazo ketones are described.The resulting γ,δ-unsaturated esters are summarized in Tables I-VI.The rearrangement is promoted by CuSO4, Cu(AcAc)2,