90201-07-3Relevant academic research and scientific papers
CHIMIE ORGANOMETALLIQUE SOUS HAUTE PRESSION: REACTION DES CHLOROCETONES AVEC L'HYDRURE DE TRIBUTYLETAIN
Degueil-Castaing, M.,Maillard, B.,Rahm, A.
, p. 49 - 56 (2007/10/02)
High-pressure reaction of tributyltin hydride with several chloroketones (3-chloro-2-butanone, 4-chloro-2-butanone, 5-chloro-2-pentanone, 6-chloro-2-hexanone and 7-chloro-2-heptanone) led to the formation of chloroalkoxytins or cyclic ethers.An ionic mechanism, starting with nucleophilic attack at the carbonyl group, is proposed to explain the formation of the reaction products.
