4091-39-8Relevant articles and documents
Ruthenium sulfophthalocyanine catalyst for the oxidation of chlorinated olefins with hydrogen peroxide
Bressan, Mario,Celli, Nicola,D'Alessandro, Nicola,Liberatore, Lolita,Morvillo, Antonino,Tonucci, Lucia
, p. 416 - 420 (2000)
In aqueous solution and at room temperature, various α-chloro-alkenes are effectively dechlorinated by hydrogen peroxide oxidation using a water-soluble ruthenium(II)-tetrasulfophthalocyanine catalyst, RuPcS. The molecular structure of RuPcS has been elucidated by ESI-mass spectroscopy. In the reaction conditions, and specifically in acidic media, the complex rapidly gives rise to a novel species, most likely catalytically active, whose nature is investigated.
A kind of 3,4-dichloro-thiazole derivatives and process for their preparation and use
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Paragraph 0042-0043; 0093-0094, (2016/10/08)
The invention provides 3,4-dichloro isothiazole derivatives, their preparation method and application. The invention relates to a heterocyclic compound containing 3,4-dichloro isothiazol, and the compound is represented by the following chemical structural general formula. The invention discloses the structural general formula of the compound, a synthetic method of the compound and applications of the compound as pesticide, bactericide, anti-plant virus agent, and plant activator, and a technology of mixing the compound with agriculturally acceptable auxiliary agents or synergists for preparing pesticide, bactericide, anti-plant virus agent, and plant activator. The invention further discloses the combined application of the compound and the commercial pesticide, bactericide, anti-plant virus agent, and plant activator in controlling diseases, insect pests, and virus diseases in agriculture, forestry and gardening, and a preparation method of the compound and the commercial pesticide, bactericide, anti-plant virus agent, and plant activator.
Chlorination of various substrates in subcritical carbon tetrachloride
Tanemura, Kiyoshi,Suzuki, Tsuneo,Nishida, Yoko,Horaguchi, Takaaki
experimental part, p. 2881 - 2888 (2010/06/16)
Various aliphatic hydrocarbons and the side chains of aromatic hydrocarbons were chlorinated in subcritical carbon tetrachloride. Chlorination of aromatic compounds including 1,4-disubstituted benzenes was investigated. Ketones and sulfones were stable under the employed conditions. Sulfoxides were converted into sulfides in a low to modest yields. The coupling adducts between olefins and carbon tetrachloride were obtained from the reactions of olefins.