902451-94-9

Basic information

• Product Name: (2S,3S)-Toluene-4-sulfonic acid 2-methyl-3-[3-methyl-3-(tetrahydropyran-2-yloxy)butyl]oxiranylmethyl ester
• Synonyms: (2S,3S)-Toluene-4-sulfonic acid 2-methyl-3-[3-methyl-3-(tetrahydropyran-2-yloxy)butyl]oxiranylmethyl ester
• CAS NO: 902451-94-9
• Molecular Weight: 412.547
• Mol File: 902451-94-9.mol

Chemical Properties

• CAS DataBase Reference: (2S,3S)-Toluene-4-sulfonic acid 2-methyl-3-[3-methyl-3-(tetrahydropyran-2-yloxy)butyl]oxiranylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-Toluene-4-sulfonic acid 2-methyl-3-[3-methyl-3-(tetrahydropyran-2-yloxy)butyl]oxiranylmethyl ester(902451-94-9)
• EPA Substance Registry System: (2S,3S)-Toluene-4-sulfonic acid 2-methyl-3-[3-methyl-3-(tetrahydropyran-2-yloxy)butyl]oxiranylmethyl ester(902451-94-9)

Safety Data

• Hazardous Substances Data: 902451-94-9(Hazardous Substances Data)

Upstream product

• 1462-10-8 4-methyl-1,4-pentanediol 
• 360066-64-4 2,6-Dimethyl-6-(tetrahydropyran-2-yloxy)hept-2-enoic acid ethyl ester 
• 30414-37-0 5,5-dimethyltetrahydrofuran-2-ol 
• 14092-32-1 2-methyl-5-<(tetrahydro-2H-pyran-2-yl)-oxy>-3-pentyn-2-ol 
• 3123-97-5 dihydro-5,5-dimethyl-2(3H)-furanone 
• 360066-65-5 2,6-Dimethyl-6-(tetrahydropyran-2-yloxy)hept-2-en-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 360066-66-6 (2S,3S)-{2-Methyl-3-[3-methyl-3-(tetrahydropyran-2-yloxy)butyl]oxiranyl}methanol 
• 360066-63-3 (E)-6-Hydroxy-2,6-dimethylhept-2-enoic acid ethyl ester 
• 10605-66-0 4-methyl-2-pentyn-1,4-diol 

Downstream Products

• 902451-99-4 (E)-(S)-4-Benzyloxy-3,7-dimethyl-oct-2-ene-1,7-diol 
• 902452-00-0 (Z)-(S)-4-Benzyloxy-3,7-dimethyl-oct-2-ene-1,7-diol 
• 902451-97-2 (E)-(S)-4-Benzyloxy-7-hydroxy-3,7-dimethyl-oct-2-enal 
• 902451-98-3 (Z)-(S)-4-Benzyloxy-7-hydroxy-3,7-dimethyl-oct-2-enal 

Relevant articles and documents

Use of nitriles in synthesis. First total synthesis of ent-sachalinol A

The total synthesis of ent-sachalinol A, has been achieved by utilizing a Sharpless epoxidation and nitrile substitution as the key reactions. Georg Thieme Verlag Stuttgart.

Stereoselective Synthesis of 2,2,6,6-Tetrasubstituted Tetrahydropyrans

A new entry to the synthesis of 3-hydroxy-2,2,6,6-tetrasubstituted tetrahydropyrans has been achieved, avoiding problems encoutered in the use of double bond assisted endo-tet cyclization reactions. These compounds are precursors of β-pyrones present in antiviral compounds.