90270-38-5Relevant academic research and scientific papers
REGIOSELECTIVE RING CLEAVAGE OF OXIRANES CATALYZED BY ORGANOTIN HALIDE - TRIPHENYLPHOSPHINE COMPLEX
Shibata, Ikuya,Baba, Akio,Matsuda, Haruo
, p. 3021 - 3024 (2007/10/02)
Vicinal chloroesters are formed in high yield from the reaction of oxiranes and benzoyl chloride in the presence of organotin halide - triphenylphosphine complex with enhanced regioselectivity in oxirane ring cleavage.
ANOMALOUS ADDITION OF TELLURIUM TETRACHLORIDE TO ALLYLIC ESTERS. SHORT SYNTHESIS OF TRANS-(2S,3S)-2,3-EPOXYBUTANE.
Engman
, p. 3977 - 3984 (2007/10/02)
The addition of tellurium to various allylic esters, alcohols, ethers, amides, and imino esters was studied. Allylic esters did not produce normal 1,2-chlorotelluration products, but the addition occurred 1,3 and was accompanied by a 1,2-migration of the acyloxy group. The examples include esters of allyl, alpha -methylallyl, alpha alpha -dimethylallyl, alpha -ethylallyl, methallyl, and (E)-crotyl alcohol, usually with benzoic acid but also with acetic, cinnamic, and crotonic acids.
