90284-45-0Relevant academic research and scientific papers
PHOTOREACTION OF α-PHENYLCROTONONITRILE DERIVATIVES: THE FACILE CYCLOPROPANE RING FORMATION
Kumagai, Tsutomu,Segawa, Toru,Endo, Zen-Ichirou,Mukai, Toshio
, p. 6225 - 6228 (2007/10/02)
Irradiation of 4-methyl, 4,4-dimethyl, and 4,4,4-trimethyl derivatives of 2-phenylcrotononitril gives the corresponding 1-cyano-1-phenyl-cyclopropanes in high yields.
NOVEL PREPARATION OF CYANOPHENYLCYCLOPROPANES VIA CYANOPHENYLCARBENE
Moss, Robert A.,Kmiecik-Lawrynowicz, Grazyna,Cox, D. Phillip
, p. 21 - 26 (2007/10/02)
Bromophenyldiazirine (1) is converted to cyanophenyldiazirine (2) upon stirring with tetra-n-butylammonium cyanide.Photolysis of 2 affords cyanophenylcarbene which is readily trapped by alkenes to yield cyanophenylcyclopropanes.
